This paper reports on the synthesis of glassy nanostructures in which the framework is a facecen tered cubic lattice of inverse yablonovite with a disordered glassy superstructure. The synthesis has been per formed by the direct laser writing method based on twophoton polymerization of a photosensitive material. The fabricated structures have been investigated using scanning electron microscopy. A theoretical calcula tion of the photonic band structures of the direct yablonovite and the inverse yablonovite has been carried out.